A Smart Phosphine–Diyne Polymer Displays “Turn-On” Emission with a High Selectivity for Gold(I/III) Ions
Harvey K. MacKenzie, Benjamin W. Rawe, Kerim Samedov, Henry T. G. Walsgrove, Azalea Uva, Zeyu Han, Derek P. Gates
Abstract
A polymeric phosphine sensor is reported that exhibits bright blue fluorescence in the presence of gold(I/III) ions but is nonemissive with other metal ions. Specifically, solutions of a poly(p-arylenediethynylene phosphine) copolymer are 35 or 94 times more emissive when treated with solutions of (tht)AuCl or HAuCl4·3H2O, respectively. Model compound studies confirm phosphine coordination to metals, including gold(I/III) and rhodium(I), and the selective “turn-on” fluorescence was investigated using time-dependent density functional theory calculations.
Topics & Concepts
PhosphineChemistrySelectivityIonRhodiumFluorescenceMetal ions in aqueous solutionTurn (biochemistry)PhotochemistryPolymerInorganic chemistryPolymer chemistryOrganic chemistryCatalysisQuantum mechanicsBiochemistryPhysicsOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsLuminescence and Fluorescent Materials