Boron containing metal–organic framework for highly selective photocatalytic production of H<sub>2</sub>O<sub>2</sub>by promoting two-electron O<sub>2</sub>reduction
Yujie Li, Fahao Ma, Liren Zheng, Yuanyuan Liu, Zeyan Wang, Peng Wang, Zhaoke Zheng, Hefeng Cheng, Ying Dai, Baibiao Huang
Abstract
The adsorption sites of boron in UiO-66-B lead to in a larger amount of O 2 adsorption; and the H + is adsorbed on the oxygen adjacent to boron, which is more conducive to the proton coupling reaction of ˙O 2 − to H 2 O 2 in the second step.
Topics & Concepts
BoronAdsorptionMetalProtonPhotocatalysisOxygenMaterials scienceElectronInorganic chemistryPhotochemistryChemistryCatalysisPhysical chemistryOrganic chemistryMetallurgyQuantum mechanicsPhysicsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsPerovskite Materials and Applications