Lemniscular carbon nanohoops with contiguous conjugation from planar chiral [2.2]paracyclophane: influence of the regioselective synthesis on topological chirality
Jing He, Mohan Yu, Zhe Lian, Yanqing Fan, Shengzhu Guo, Xiaonan Li, Ying Wang, Wenguang Wang, Zhi-Yun Cheng, Hua Jiang
Abstract
We report herein two lemniscular carbon nanohoops bis-po-CC and bis-pm-TC with contiguous conjugation from planar chiral [2.2]paracyclophane, and elucidate the influence of the regioselective synthesis on their topological chirality.
Topics & Concepts
RegioselectivityChirality (physics)Planar chiralityPlanarTopology (electrical circuits)Enantioselective synthesisStereochemistryMaterials scienceChemistryPhysicsComputer scienceOrganic chemistryMathematicsChiral symmetryCatalysisCombinatoricsQuantum mechanicsNambu–Jona-Lasinio modelQuarkComputer graphics (images)Synthesis and Properties of Aromatic CompoundsSupramolecular Chemistry and ComplexesSurface Chemistry and Catalysis