Chromone-Based Cd(II) Fluorescent Coordination Polymer Fabricated to Study Optoelectronic and Explosive Sensing Properties
Jayanta Mandal, Arka Dey, Sourav Sarkar, Mohafuza Khatun, Pravat Ghorai, Partha Pratim Ray, Partha Mahata, Amrita Saha
Abstract
Here, electrical conductivity and explosive sensing properties of multifunctional chromone-Cd(II)-based coordination polymers (CPs) ( 1 – 4 ) have been explored. The presence of different pseudohalide linkers, thiocyanate ions, and dicyanamide ions resulted in 1D and 3D architecture in the CPs. Thin film devices developed from CPs 1 – 4 (complex-based Schottky devices, CSD1, CSD2, CSD3, and CSD4, respectively) showed semiconductor behavior. Their conductivity values increased under photo illumination (1.37 × 10 –5, 1.85 × 10 –5, 1.61 × 10 –5, and 2.01 × 10 –5 S m –1 under dark conditions and 5.06 × 10 –5, 8.78 × 10 –5, 7.26 × 10 –5, and 10.21 × 10 –5 S m –1 under light). The nature of the I – V plots of these thin film devices under light irradiation and dark are nonlinear rectifying, which has been observed in Schottky barrier diodes (SBDs). All four CPs ( 1 – 4 ) exhibited highly selective fluorescence quenching-based sensing properties toward well-known explosives, 2,4-dinitrophenol (DNP) and 2,4,6-trinitrophenol (TNP). The limit of detection (LOD) values are 55, 28, 27, and 31 μM for TNP and 78, 44, 32, and 41 μM for DNP for complexes 1 – 4, respectively. A structure property correlation has been established to explain optoelectronic and explosive sensing properties.