Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF<sub>3</sub>SO<sub>2</sub>Na
Wenhao Long, Pengcheng Lian, Jingjing Li, Xiaobing Wan
Abstract
This work demonstrated the photoinduced hydroxytrifluoromethylation of aliphatic alkenes catalysed by Mn(acac)3. The synthesis uses an inexpensive catalyst under mild reaction conditions, and exhibits a wide substrate scope and excellent functional group tolerance.
Topics & Concepts
ChemistryAlkenePhotoredox catalysisPhotochemistryCatalysisOrganic chemistryPhotocatalysisFluorine in Organic ChemistryInorganic Fluorides and Related CompoundsRadical Photochemical Reactions