Enhancing CoFe Catalysts with V <sub>2</sub> CT <sub>X</sub> MXene‐Derived Materials for Anion Exchange Membrane Electrolyzers
C. Kaplan, Karuppasamy Dharmaraj, Thorsten Schultz, Leiqiang Qin, Ningjun Chen, Danielle Douglas-Henry, Bastian Schmiedecke, Merve Buldu-Aktürk, Axel Zuber, Iris Dorbandt, Maximilian Reinhardt, Yael Rodriguez‐Ayllon, Yan Lü, Valeria Nicolosi, Norbert Koch, Johanna Rosén, Michelle P. Browne
Abstract
Abstract Herein, the synthesis and characterization of Co 0.66 Fe 0.34 layered double hydroxides (LDH) derived from pure and vacancy‐engineered V 2 CT x MXenes and their use as electrocatalysts for the oxygen evolution reaction (OER) is reported. Two distinct MXene materials are investigated: pristine V 2 CT x and V 1.8 CT x containing 10% vanadium vacancies. Through systematic variation of the MXene content (17–75 wt.%), it demonstrates that the utilization of MXenes significantly enhances OER activity compared to pure Co 0.66 Fe 0.34 . The vacancy‐engineered composite Co 0.66 Fe 0.34 @V 1.8 CT x achieved superior performance with an overpotential of 304 mV at 10 mA cm −2 (CFVv75), compared to 317 mV for the best‐performing V 2 CT x MXene composite (CFV33). In situ X‐Ray absorption spectroscopy revealed the formation of highly oxidized Co (i.e., Co(III) and Co(IV)) species during OER, while also indicating irreversible oxidation of vanadium to V(V). Despite partial vanadium leaching, both materials demonstrated excellent stability over 12 h of operation at 100 mA cm −2 . Notably, CFVv75 showed superior initial performance under practical anion exchange membrane electrolyzer conditions, operating at cell voltages of 100 mV lower than the pure Co 0.66 Fe 0.34 . This work demonstrates the potential of vacancy engineering and materials discovery using MXene materials for enhancing electrocatalytic performance and provides insights into the dynamic evolution of these materials under operating conditions.