Unveiling Temperature-Induced Structural Phase Transformations and CO<sub>2</sub> Binding Sites in CALF-20
Joanna Drwęska, Filip Formalik, Kornel Roztocki, Randall Q. Snurr, Leonard J. Barbour, Agnieszka Janiak
Abstract
High Resolution Image Download MS PowerPoint Slide The increase in atmospheric carbon dioxide concentration linked to climate change has created a need for new sorbents capable of separating CO 2 from exhaust gases. Recently, an easily produced metal–organic framework, CALF-20, was shown to withstand over 450,000 adsorption/desorption cycles in steam and wet acid gases. Further development and industrial application of such materials require an understanding of the observed processes. Herein, we demonstrate that conditioning as-synthesized CALF-20 single crystal transforms it into a different phase, γ-CALF-20. The transformation resulted in significant structural changes, including the binding of water molecules to Zn(II), accompanied by a reduction of 9% in the unit cell volume. Our experimental findings were supported by the energy-volume dependence of CALF-20 in the presence and absence of water molecules calculated from density functional theory. We have also monitored the sorption process of the dominant greenhouse gas, CO 2, on the initial phase of CALF-20 at atomic resolution using in situ single-crystal X-ray diffraction under specific pressure. The new understanding of CALF-20 chemistry from these studies should facilitate development of novel sorbents for gas adsorption technologies.