A photoredox- or metal-catalyzed three-component cyanoalkylsulfonylation reaction of 1-(allyloxy)-2-(1-arylvinyl)benzenes, potassium metabisulfite, and cycloketone oxime esters: synthesis of cyanoalkylsulfonylated benzoxepines
Nengneng Zhou, Sixin Wu, Kaimo Kuang, Ziqin Xia, Qiankun Xu, Man Zhang
Abstract
A visible light photocatalyzed or metal-catalyzed three-component cyanoalkylsulfonylation of 1-(allyloxy)-2-(1-arylvinyl)benzenes, potassium metabisulfite and cyclobutanone oxime esters is developed.
Topics & Concepts
ChemistryOximeCatalysisPotassiumMetalMedicinal chemistryOrganic chemistryPhotochemistrySulfur-Based Synthesis TechniquesRadical Photochemical ReactionsChemical Synthesis and Reactions