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Recent advances in the transition metal-free oxidative dehydrogenative aromatization of cyclohexanones

Kun Deng, Huawen Huang, Guo‐Jun Deng

2021Organic & Biomolecular Chemistry45 citationsDOI

Abstract

Cyclohexanone is a simple and widely available raw material that can be obtained from lignin biomass, highlighting its renewable and sustainable features. Cyclohexanone, as an important synthon in organic chemistry, has been demonstrated to be viable for constructing functionalized arenes and benzoheteroarenes, with recent extensive development on transition metal-free oxidative dehydrogenative aromatization. This review focuses on recent research progress on the transition metal-free derivation of cyclohexanones via oxidative dehydrogenative aromatization.

Topics & Concepts

AromatizationOxidative phosphorylationTransition metalChemistryPhotochemistryEnvironmental chemistryEnvironmental scienceOrganic chemistryBiochemistryCatalysisCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsChemical Synthesis and Reactions
Recent advances in the transition metal-free oxidative dehydrogenative aromatization of cyclohexanones | Litcius