A new series of 3D lanthanide phenoxycarboxylates: synthesis, crystal structure, magnetism and photoluminescence studies
Rupam Sen, Sanchayeeta Paul, Alolika Sarkar, Alexandre M. P. Botas, Albano N. Carneiro Neto, Paula Brandão, A. M. L. Lopes, Rute A. S. Ferreira, João P. Araújo, Zhi Lin
Abstract
A new series of 3D Ln-carboxylates was synthesized, where the Tb one shows antiferromagnetic coupling and the Dy one shows ferromagnetic interaction, and with emission spectra combining the intra-4f emission of the Ln ions and that of the ligand.
Topics & Concepts
MagnetismPhotoluminescenceLanthanideAntiferromagnetismSeries (stratigraphy)FerromagnetismIonCrystallographyMaterials scienceCoupling (piping)Ligand (biochemistry)Spectral lineCrystal structureEmission spectrumChemistryCondensed matter physicsPhysicsOptoelectronicsMetallurgyGeologyReceptorOrganic chemistryPaleontologyAstronomyBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes