Size dependent electronic structure of LiFePO<sub>4</sub> probed using X-ray absorption and Mössbauer spectroscopy
Mahboob Ali, Nataliya Tsud, Sher Singh Meena, Sevi Murugavel
Abstract
orbitals. The unique structural and electronic properties of LFP are closely interlinked with changes in the bonding character, which shows the strong dependency on CS. The evolution of 3d states is in overall agreement with the local lattice distortion and provides the origin of the size effects on the electronic structure of olivine phosphate and other transition metal ion-containing materials.
Topics & Concepts
Electronic structureValence (chemistry)Absorption spectroscopyChemistryIonValencySpectroscopyMössbauer spectroscopyCrystallographyComputational chemistryPhysicsLinguisticsOrganic chemistryQuantum mechanicsPhilosophyAdvancements in Battery MaterialsAdvanced Battery Materials and TechnologiesMagnetic Properties and Synthesis of Ferrites