Tetrel bonding stabilization of a new coordination polymer constructed from lead(<scp>ii</scp>) azide and 1-(pyridin-2-yl)ethylidenepicolinohydrazide
Ghodrat Mahmoudi, Ennio Zangrando, Atash V. Gurbanov, Bagher Eftekhari‐Sis, Mariusz P. Mitoraj, Filip Sagan, Damir A. Safin
Abstract
A coordination polymer [Pb 3 L 2 (N 3 ) 4 ] n constructed from Pb(N 3 ) 2 and 1-(pyridin-2-yl)ethylidenepicolinohydrazide ( HL ), and computational studies of non-covalent interactions and their physical contributions (Pb⋯N, N⋯N, C–H⋯N and π⋯π) are reported.
Topics & Concepts
AzideCovalent bondPolymerChemistryCoordination polymerPolymer chemistryCrystallographyStereochemistryMedicinal chemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCrystal structures of chemical compoundsCrystallography and molecular interactions