Multiscale understanding the effect of K/Na ratio on electrical properties of high‐performance KNN‐based ceramics
Yifeng Huang, Xin Wang, Yinchang Ma, Xiang Lv, Jiagang Wu
Abstract
Abstract Although certain efforts were paid to the effect of K/Na ratio on the phase structure and piezoelectric properties of potassium sodium niobate {(K, Na)NbO 3 , KNN}‐based ceramics, insufficient attention was given to the local structure and ferroelectric domains, hindering the further understanding of physical mechanisms. Herein, we studied the effect of the K/Na ratio on KNN‐based ceramics with multi‐phase coexistence from multiscale structure. High Na + content leads to local stress heterogeneity and retains large ferroelectric domains, while high K + content rotates the NbO 6 octahedron and results in local polarity heterogeneity and distinct dielectric relaxational behavior, consequently fragmenting ferroelectric domains. The improved piezoelectricity is obtained at the equal K/Na ratio and originates from the balanced local polarity and stress heterogeneities. Therefore, an appropriate K/Na ratio should be fully considered when designing compositions with the purpose of improving performance of KNN‐based ceramics in the future.