Gold and palladium supported on an ionic liquid modified Fe-based metal–organic framework (MOF) as highly efficient catalysts for the reduction of nitrophenols, dyes and Sonogashira–Hagihara reactions
Shirin Karimi, Mohammad Gholinejad, Rahimeh Khezri, José M. Sansano, Carmén Nájera, Miguel Yus
Abstract
, methylene blue (MB), methyl orange (MO), and methyl red (MR) were performed efficiently in water. On the other hand, Pd@Fe-MOF-IL was used as an effective catalyst in the Sonogashira-Hagihara coupling reaction of aryl iodides and bromides using very low amounts of Pd. These catalysts were recycled and reused for several runs without deteriorating remarkably in catalytic performance.
Topics & Concepts
Sonogashira couplingIonic liquidPalladiumCatalysisMetal-organic frameworkNoble metalChemistryIonic bondingMetalInorganic chemistryOrganic chemistryIonAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis