Phenethylamine ligand engineering of red InP quantum dots for improving the efficiency of quantum dot light-emitting diodes
Wei Jiang, Bo-Ram Kim, Heeyeop Chae
Abstract
In this Letter, red-emitting multi-shelled indium phosphide (InP) quantum dots (QDs) were synthesized using the safe phosphorus precursor tris(dimethylamino)phosphine ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo stretchy="false">(</mml:mo> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">D</mml:mi> <mml:mi mathvariant="normal">M</mml:mi> <mml:mi mathvariant="normal">A</mml:mi> </mml:mrow> </mml:mrow> <mml:msub> <mml:mo stretchy="false">)</mml:mo> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">P</mml:mi> </mml:mrow> </mml:mrow> </mml:math> ). The long-chain ligands of oleylamine (OAm) in the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo stretchy="false">(</mml:mo> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">D</mml:mi> <mml:mi mathvariant="normal">M</mml:mi> <mml:mi mathvariant="normal">A</mml:mi> </mml:mrow> </mml:mrow> <mml:msub> <mml:mo stretchy="false">)</mml:mo> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">P</mml:mi> </mml:mrow> </mml:mrow> </mml:math> phosphide source-based InP QDs were partially exchanged with short-chain ligands of phenethylamine (PEA) in the core formation process, and the resulting InP QDs were applied to quantum dot light-emitting diodes (QLEDs). The short-chain ligands of PEA with the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mi>π</mml:mi> </mml:math> -conjugated benzene ring improved the charge transport and electrical conduction of the QLEDs with <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo stretchy="false">(</mml:mo> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">D</mml:mi> <mml:mi mathvariant="normal">M</mml:mi> <mml:mi mathvariant="normal">A</mml:mi> </mml:mrow> </mml:mrow> <mml:msub> <mml:mo stretchy="false">)</mml:mo> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">P</mml:mi> </mml:mrow> </mml:mrow> </mml:math> phosphide source-based InP QDs. The PEA-engineering of InP QDs improved their maximum quantum yield from 71% to 85.5% with the full-width at half-maximum of 62 nm. Furthermore, the maximum external quantum efficiency of QLEDs with the PEA-engineered InP QDs improved from 1.9% to 3.5%, and their maximum power efficiency increased from 2.8 to 6.0 lm/W. This Letter demonstrates that engineering the core formation process with the short-chain ligands of PEA provides an efficient and facile way to improve the charge transport and electrical conduction in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo stretchy="false">(</mml:mo> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">D</mml:mi> <mml:mi mathvariant="normal">M</mml:mi> <mml:mi mathvariant="normal">A</mml:mi> </mml:mrow> </mml:mrow> <mml:msub> <mml:mo stretchy="false">)</mml:mo> <mml:mn>3</mml:mn> </mml:msub> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">P</mml:mi> </mml:mrow> </mml:mrow> </mml:math> phosphide source-based InP QLEDs for electroluminescent devices.