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Towards advanced remediation: CuS/CdS Z-scheme heterojunction with accelerated charge-transfer for efficient photocatalytic degradation of trypan blue

Samina Kousar, M. Abdel Rafea, Magdi E. A. Zaki, M. Khaіry, Mohamed R. El‐Aassar, ‏Abdullah K. Alanazi, Imran Shakir, Sidra Mubeen, Muhammad Aadil

2025RSC Advances7 citationsDOIOpen Access PDF

Abstract

) exhibited the highest reactivity among the species tested. Calculations of band edge potential have verified that the Z-scheme charge transfer mechanism facilitates efficient charge separation and the generation of reactive oxygen species (ROS). Curiously, the pH of the heterogeneous composite was found to be correlated with its photocatalytic activity. An examination of the pH level disclosed a PZC value of 5.39. The composite functioned most effectively at a pH of 4. A novel CuS/CdS composite has been explored that is not only novel but is also ecological, cost-effective, and structurally stable in mineralizing the persistent azo dyes.

Topics & Concepts

PhotocatalysisMaterials scienceHeterojunctionAbsorption edgeChemical engineeringNanocompositeComposite numberBand gapX-ray photoelectron spectroscopyPhotochemistryDegradation (telecommunications)Charge carrierReaction rate constantAdsorptionAbsorption (acoustics)Visible spectrumTrypan blueCrystal (programming language)NanotechnologyPoint of zero chargeRadicalAnalytical Chemistry (journal)Advanced Photocatalysis TechniquesAdvanced Nanomaterials in CatalysisQuantum Dots Synthesis And Properties
Towards advanced remediation: CuS/CdS Z-scheme heterojunction with accelerated charge-transfer for efficient photocatalytic degradation of trypan blue | Litcius