Effect of Nano‐Copper Chromite on the Thermal Decomposition and Combustion of AP‐Based Solid Propellants
Bingwang Gou, Yong Kou, Yubing Hu, Guangpu Zhang, Hu Guo, Lei Xiao, Fengqi Zhao, Hongxu Gao, Wei Jiang, Gazi Hao
Abstract
Abstract This investigation was devoted to exploring the application performance of nano‐combustion catalyst CuCr 2 O 4 in solid propellants. In this paper, raw CuCr 2 O 4 and nano‐CuCr 2 O 4 prepared by the mechanical grinding method were applied in solid propellants containing ammonium perchlorate (AP), which are ammonium perchlorate/ hydroxy‐terminated polybutadiene propellant (AP/HTPB) and ammonium perchlorate/composite modified double‐base propellant (AP/CMDB). And the scanning electron microscope, displacement volume method, thermogravimetric analysis, differential scanning calorimetry, and strand burner method were employed to characterize the performance of AP‐based solid propellants. The results show that the AP/HTPB propellant has fewer defects on the surface of it due to the presence of nano‐CuCr 2 O 4 , but it has no significant effect on the AP/CMDB propellant. Nano‐CuCr 2 O 4 can also significantly increase the density of AP/HTPB propellant and AP/CMDB propellant to 1.736 g/cm 3 and 1.633 g/cm 3 , respectively. Nano‐CuCr 2 O 4 obviously advances the decomposition temperature of AP/HTPB propellant and AP/CMDB propellant, which also increases the apparent heat of decomposition. In addition, the burning rate of nano‐CuCr 2 O 4 ‐AP/HTPB propellant and nano‐CuCr 2 O 4 ‐AP/CMDB propellant increased to 1.60 mm/s and 3.23 mm/s, with an increase of 28.3 % and 26.3 %, respectively. Therefore, nano‐CuCr 2 O 4 is expected to be widely used in solid propellants due to its excellent properties.