Challenging Metathesis Catalysts with Nucleophiles and Brønsted Base: Examining the Stability of State-of-the-Art Ruthenium Carbene Catalysts to Attack by Amines
Daniel L. Nascimento, Immanuel Reim, Marco Foscato, Vidar R. Jensen, Deryn E. Fogg
Abstract
ligand were comparatively insensitive to amines, owing to rapid, preferential bimolecular decomposition.
Topics & Concepts
CarbeneMorpholineChemistryNucleophileRutheniumMedicinal chemistryCatalysisMetathesisSalt metathesis reactionOrganic chemistryPolymerizationPolymerSynthetic Organic Chemistry MethodsCatalytic Cross-Coupling ReactionsOrganometallic Complex Synthesis and Catalysis