Encapsulation of Tinospora cordifolia plant in Ni doped TiO2 nanoparticles for the degradation of malachite green dye
Naveen Thakur, Nikesh Thakur, Kuldeep Kumar, Vedpriya Arya, Ashwani Kumar
Abstract
The primary global source of water pollution is textile dyes. Highly stable organic dyes are produced by these industries that are released untreated into nearby ponds, lakes and rivers. This paper is devoted to synthesis of nickle doped anatase phase of TiO2 nanoparticles (Ni-ATD NPs) by encapsulating plant Tinospora cordifolia (TC) through microwave assisted method for degradation of malachite green (MG) dye. The synthesized NPs were calcinated at 400 oC temperature to achieve the anatase phase. The synthesized Ni-ATD NPs were analysed with different characterization methods. X-ray diffraction (XRD) and Raman analysis confirmed the crystalline nature for Ni-ATD NPs with a tetragonal structure having crystallite size of 11 nm. Scanning electron microscope (SEM) determined the spherical surface morphology for synthesized NPs. The absorption peaks of Ni-ATD NPs were originated from 360 to 370 nm from UV-Visible spectroscopy in which the bandgap was found to be 3.45 eV. The photocatalytic activity for MG dye was evaluated under ultra-violet (UV) light using Ni-ATD NPs for 90 minutes which exhibited the degradation up to 100 %.