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Spray and evaporation characteristics of high-pressure liquid ammonia injection under flash-boiling and evaporating conditions

Haoqing Wu, Shijie Mi, Yong Qian, Tianhao Zhang, Jinhe Zhang, Cheng Pan, Lei Shi, Xingcai Lu

2024Fuel32 citationsDOIOpen Access PDF

Abstract

Ammonia, as an efficient hydrogen carrier, is considered a promising zero-carbon alternative fuel for energy systems. High-pressure liquid ammonia injection enables efficient and clean utilization of ammonia in energy devices. This study systematically investigates the spray and evaporation characteristics of high-pressure liquid ammonia spray with two different nozzle diameters (0.1 mm and 0.3 mm) over wide operating conditions by combining high-speed DBI and shadowgraph techniques. The results indicate that the expansion rate of the small-nozzle spray is greater than that of the large-nozzle spray at low superheat (1.4 ∼ 2). As the superheat exceeds 2, the spray expands significantly radially, with a larger expansion rate for the large-nozzle spray, suggesting the large-nozzle spray is more prone to forming flash-boiling bubbles. Under high temperature and pressure conditions with fixed ambient pressure, the liquid penetration increases and then decreases as the temperature increases, and the inflection point temperature of the large-nozzle spray is higher. Compared with diesel, the axial diffusion of the liquid ammonia is larger while the radial diffusion is smaller. There is a post-supercooling residual region affected by the pilot-evaporated ammonia in the capturing and recirculation regions, where the fuel cannot completely evaporate like the diesel. This characteristic should be considered when designing the liquid ammonia spray system.

Topics & Concepts

EvaporationFlash evaporationBoilingAmmoniaFlash (photography)Liquid ammoniaChemistryHigh pressureVaporizationSuperheatingMaterials scienceThermodynamicsChromatographyOrganic chemistryVisual artsArtPhysicsElectrohydrodynamics and Fluid DynamicsAdvanced Combustion Engine TechnologiesCombustion and flame dynamics
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