Selective synthesis and (chir)optical properties of binaphthyl-based chiral carbon macrocycles
Pengwei Fang, Muqing Chen, Xinyu Zhang, Pingwu Du
Abstract
Two novel chiral carbon macrocycles containing chiral binaphthyl units were synthesized, which demonstrate significant redshifts in emission compared to chiral binaphthyl units and have good chiroptical properties.
Topics & Concepts
Circular dichroismChirality (physics)LuminescencePlanar chiralityMaterials scienceAsymmetric carbonPlanarCrystallographyCarbon fibersChemistryPhotochemistryStereochemistryOptically activeEnantioselective synthesisChiral symmetryOrganic chemistryOptoelectronicsCatalysisComposite materialQuantum mechanicsComposite numberNambu–Jona-Lasinio modelQuarkPhysicsComputer graphics (images)Computer scienceSynthesis and Properties of Aromatic CompoundsAxial and Atropisomeric Chirality SynthesisMolecular spectroscopy and chirality