Experimental evidence for glass polymorphism in vitrified water droplets
Johannes Bachler, Johannes Giebelmann, Thomas Loerting
Abstract
Significance The question of whether a first-order liquid-to-liquid transition is at the origin of water’s anomalous properties has been controversial since the pioneering experiments by Mishima et al. in 1985 and molecular simulations by Poole et al. in 1992. Since then, experiments aimed at shedding light on this question have been performed using amorphous ices made from crystalline ice, fueling criticism about their crystal-like nature. In the present study, we avoid crystalline ice at any time of the experiment yet still observe a first-order glass-to-glass transition in vitrified liquid droplets. This makes the strong case for glass polymorphism and the direct thermodynamic connection to the liquid-to-liquid transition at higher temperatures, dismissing the criticism voiced for three decades.