DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds
Richard Holzner, Dominik Reiter, Philipp Frisch, Shigeyoshi Inoue
Abstract
DMAP-stabilized silylenes <bold>1a–c</bold>, which are convenient, room temperature stable synthetic equivalents for the corresponding highly reactive free bis(silyl)silylenes are reported.
Topics & Concepts
OrganosiliconSilylationSynthonChemistryIsomerizationSiliconPhotochemistryPolymer chemistryOrganic chemistryCatalysisSynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryCoordination Chemistry and Organometallics