High intrinsic lattice thermal conductivity in monolayer MoSi<sub>2</sub>N<sub>4</sub>
Jihai Yu, Jian Zhou, Xiangang Wan, Qingfang Li
Abstract
Abstract Very recently, a novel two-dimension (2D) MXene, MoSi 2 N 4 , was successfully synthesized with excellent ambient stability, high carrier mobility, and moderate band gap (2020 Science 369 670). In this work, the intrinsic lattice thermal conductivity of monolayer MoSi 2 N 4 is predicted by solving the phonon Boltzmann transport equation based on the first-principles calculations. Despite the heavy atomic mass of Mo and complex crystal structure, the monolayer MoSi 2 N 4 unexpectedly exhibits a quite high lattice thermal conductivity over a wide temperature range between 300 to 800 K. At 300 K, its in-plane lattice thermal conductivity is 224 Wm −1 K −1 . The detailed analysis indicates that the large group velocities and small anharmonicity are the main reasons for its high lattice thermal conductivity. We also calculate the lattice thermal conductivity of monolayer WSi 2 N 4 , which is only a little smaller than that of MoSi 2 N 4 . Our findings suggest that monolayer MoSi 2 N 4 and WSi 2 N 4 are potential 2D materials for thermal transport in future nano-electronic devices.