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Single-atom catalysts supported on a hybrid structure of boron nitride/graphene for efficient nitrogen fixation <i>via</i> synergistic interfacial interactions

Mohammad Zafari, Rohit Anand, Arun S. Nissimagoudar, Miran Ha, Geunsik Lee, Kwang S. Kim

2023Nanoscale10 citationsDOI

Abstract

binding energy and further the band gap is reduced to zero. V (vanadium) and W (tungsten) SACs exhibit the best performance with limiting potentials of -0.22 and -0.41 V, respectively. This study helps in understanding the improvement of the NRR activity of BN, providing physical insights into the adsorbate-TM interaction.

Topics & Concepts

Boron nitrideGrapheneBoronCatalysisNitrogen fixationMaterials scienceNitrogenNitrideAtom (system on chip)Nitrogen atomChemical engineeringNanotechnologyChemistryOrganic chemistryGroup (periodic table)Layer (electronics)Computer scienceEmbedded systemEngineeringAmmonia Synthesis and Nitrogen ReductionCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions
Single-atom catalysts supported on a hybrid structure of boron nitride/graphene for efficient nitrogen fixation <i>via</i> synergistic interfacial interactions | Litcius