Phenyliodine(III)diacetate (PIDA): Applications in Organic Synthesis
Ravi Varala, Vittal Seema, Narsimhaswamy Dubasi
Abstract
One of the hypervalent iodines most widely used as an oxidizing agent in organic chemistry is (diacetoxyiodo)benzene (PhI(OAc)2), also known as (DAIB), phenyliodine(III) diacetate (PIDA). In this septennial mini-review, the authors have concisely and systematically presented representative applications of PIDA in organic synthesis involving C-H functionalization, hetero-hetero bond formations, heterocyclic ring construction, rearrangements or migrations and miscellaneous reactions along with their interesting mechanistic aspects starting from the summer of 2015 to the present.
Topics & Concepts
Hypervalent moleculeOxidizing agentOrganic synthesisChemistryBenzeneRing (chemistry)Combinatorial chemistryOrganic chemistryReagentCatalysisOxidative Organic Chemistry ReactionsSynthesis and Catalytic ReactionsCatalytic C–H Functionalization Methods