Sulfonium salt formation-triggered regio- and <i>Z</i> -stereoselective phenoxythiolation of alkynes
Mengke Su, Hanmiao Xu, Zengwei Lai, Jian Wen
Abstract
We report a sulfonium salt formation-triggered, regio- and Z -stereoselective phenoxythiolation of alkynes with phenols and sulfoxides, enabling the synthesis of sulfur-containing aryl alkenylethers under mild one-pot conditions.
Topics & Concepts
SulfoniumChemistryStereoselectivitySalt (chemistry)StereochemistrySodium saltCombinatorial chemistryMedicinal chemistryOrganic chemistryInorganic chemistryCatalysisSulfur-Based Synthesis Techniques