A {Ni<sub>12</sub>}‐Wheel‐Based Metal–Organic Framework for Coordinative Binding of Sulphur Dioxide and Nitrogen Dioxide
Zongsu Han, Jiangnan Li, Wanpeng Lu, Kunyu Wang, Yinlin Chen, Xiaoping Zhang, Longfei Lin, Xue Han, Simon J. Teat, Mark D. Frogley, Sihai Yang⧫, Wei Shi, Peng Cheng
Abstract
Abstract Air pollution by SO 2 and NO 2 has caused significant risks on the environment and human health. Understanding the mechanism of active sites within capture materials is of fundamental importance to the development of new clean‐up technologies. Here we report the crystallographic observation of reversible coordinative binding of SO 2 and NO 2 on open Ni II sites in a metal‐organic framework (NKU‐100) incorporating unprecedented {Ni 12 }‐wheels; each wheel exhibits six open Ni II sites on desolvation. Immobilised gas molecules are further stabilised by cooperative host‐guest interactions comprised of hydrogen bonds, π⋅⋅⋅π interactions and dipole interactions. At 298 K and 1.0 bar, NKU‐100 shows adsorption uptakes of 6.21 and 5.80 mmol g −1 for SO 2 and NO 2 , respectively. Dynamic breakthrough experiments have confirmed the selective retention of SO 2 and NO 2 at low concentrations under dry conditions. This work will inspire the future design of efficient sorbents for the capture of SO 2 and NO 2 .