Litcius/Paper detail

High-throughput screening of room temperature active Peltier cooling materials in Heusler compounds

Huifang Luo, Xin Li, Yuxiang Wang, Yeqing Jin, Mingjia Yao, Jiong Yang

2022npj Computational Materials16 citationsDOIOpen Access PDF

Abstract

Abstract Active Peltier cooling enables Peltier heat transfer in addition to the traditional Fourier thermal conductance, which is useful in some special applications, such as the microthermostats. From the material wise, however, the study on the active Peltier cooling materials is rare. We carried out a high-throughput workflow to screen out 5 room-temperature active Peltier cooling materials, GaSbLi 2 , HgPbCa 2 , SnTiRu 2 , GeYbLi 2 , and GeTiFe 2 , from 2958 Heusler materials. All the five materials are semimetals or very narrow band gap systems with high electrical conductivity. Some of these materials have relatively large Seebeck coefficients due to the band asymmetry. Their effective thermal conductivity κ eff s, which are the summation of active Peltier thermal conductivity and passive thermal conductivity, are all greater than Cu at the room temperature and Δ T = 1 K. The present work gives a possible way to search active cooling Peltier materials for the applications of precise temperature control.

Topics & Concepts

Thermoelectric effectThermoelectric coolingThermal conductivityMaterials scienceThermoelectric materialsOptoelectronicsThermocoupleThermodynamicsComposite materialPhysicsAdvanced Thermoelectric Materials and DevicesThermal properties of materialsHeusler alloys: electronic and magnetic properties