Electrocatalytic production of hydrogen peroxide enabled by post-synthetic modification of a self-assembled porphyrin cube
Matthew R. Crawley, Daoyang Zhang, Timothy R. Cook
Abstract
A self-assembled porphyrin cube can be metalated/transmetalated to contain fourteen cobalt ions in two different environments. The Co( ii ) metalloporphyrin sites are electrocatalytically active to selectively generate hydrogen peroxide from oxygen.
Topics & Concepts
PorphyrinHydrogen peroxideCobaltChemistryElectrocatalystCube (algebra)PhotochemistryOxygenSelf-assemblyHydrogenPolymer chemistryCombinatorial chemistryInorganic chemistryOrganic chemistryElectrochemistryElectrodePhysical chemistryMathematicsCombinatoricsElectrocatalysts for Energy ConversionPorphyrin and Phthalocyanine ChemistryElectrochemical Analysis and Applications