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Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

Qiao Xia, Xingxing Jiang, Qi Lu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark G. Humphrey, Kazuyuki Tatsumi, Chi Zhang

2024Inorganic Chemistry Frontiers14 citationsDOIOpen Access PDF

Abstract

A noncentrosymmetric phosphate (C 3 H 5 N 2 )(H 2 PO 4 ) with pseudo 2D intercalated layers, which exhibits large birefringence and wide band gap, was successfully synthesized by simultaneously introducing the planar and tetrahedral motifs.

Topics & Concepts

Layer (electronics)PhosphateAnisotropyOptical anisotropyCrystallographyMaterials scienceChemistryNanotechnologyOpticsPhysicsOrganic chemistryOptical and Acousto-Optic TechnologiesPhotorefractive and Nonlinear OpticsOptical Polarization and Ellipsometry