Extended enantiopure <i>ortho</i>-phenylene ethylene (<i>o</i>-OPE)-based helical systems as scaffolds for supramolecular architectures: a study of chiroptical response and its connection to the CISS effect
Ana M. Ortuño, Pablo Reiné, Sandra Resa, Luı́s Álvarez de Cienfuegos, Víctor Blanco, José M. Paredes, Antonio J. Mota, Giuseppe Mazzeo, Sergio Abbate, Jesús M. Ugalde, Vladimiro Mújica, Giovanna Longhi, D. Miguel, Juan M. Cuerva
Abstract
Versatile enantiopure helical systems are described and are of interest owing to their intense chiroptical responses, their attractive architecture for metallosupramolecular chemistry and CISS effect.
Topics & Concepts
Enantiopure drugChemistrySupramolecular chemistryPhenyleneEthyleneConnection (principal bundle)Supramolecular chiralityCombinatorial chemistryStereochemistryOrganic chemistryEnantioselective synthesisMoleculeGeometryMathematicsCatalysisPolymerSynthesis and Properties of Aromatic CompoundsMolecular Sensors and Ion DetectionSupramolecular Chemistry and Complexes