Cp*Co(<scp>iii</scp>) and Cu(OAc)2 bimetallic catalysis for Buchwald-type C–N cross coupling of aryl chlorides and amines under base, inert gas & solvent-free conditions

Avinash K. Srivastava, Charu Sharma, Raj K. Joshi

2020Green Chemistry18 citationsDOI

Abstract

A strategy involving bimetallic catalysis which requires a combination of Cp*Co(CO)I2 and Cu(OAc)2 was used to perform Buchwald-type C–N coupling reactions of aryl chlorides with amines.

Topics & Concepts

Bimetallic stripArylCatalysisChemistrySolventMedicinal chemistryBase (topology)InertInert gasOrganic chemistryAlkylMathematicsMathematical analysisCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and Catalysis

Cp*Co(<scp>iii</scp>) and Cu(OAc)<sub>2</sub> bimetallic catalysis for Buchwald-type C–N cross coupling of aryl chlorides and amines under base, inert gas &amp; solvent-free conditions

Abstract

Topics & Concepts

Cp*Co(<scp>iii</scp>) and Cu(OAc)<sub>2</sub> bimetallic catalysis for Buchwald-type C–N cross coupling of aryl chlorides and amines under base, inert gas & solvent-free conditions