Ultra-broad Near-Infrared Emitting Phosphor LiInF<sub>4</sub>: Cr<sup>3+</sup>with Extremely Weak Crystal Field
Liping Song, Sisi Liang, Wendong Nie, Xian-guo He, Jie Hu, Fulin Lin, Haomiao Zhu
Abstract
Recent decades have witnessed a major development in broadband near-infrared (NIR)-emitting phosphors because of their potential applications in real-time nondestructive examination. These applications require the emission spectra of phosphors to be as broad as possible for efficient performance. Therefore, a blue-light excited LiInF 4: Cr 3+ phosphor with a NIR emission covering 700–1400 nm is successfully synthesized. Under 470 nm excitation, it shows broadband emission peaked at 980 nm with the full-width at half maximum of 210 nm. The structure and crystal field environment are investigated in detail, and the LiInF 4: Cr 3+ possesses a weak crystal field strength and strong electron–phonon coupling. An efficient NIR phosphor-converted light-emitting diode (pc-LED) is fabricated by the prepared LiInF 4: Cr 3+ phosphor and commercial blue diode chip, generating a NIR radiant flux of 5.54 mW at 150 mA drive current. Finally, the NIR pc-LED is successfully applied to identify the blood vessel distribution of the hand. This work suggests the potential of LiInF 4: Cr 3+ phosphor in applications.