An octahedral polyoxomolybdate–organic molecular cage
Xinying Wang, Wei‐Chao Chen, Kui‐Zhan Shao, Xinlong Wang, Liang Zhao, Zhong-Min Su
Abstract
An unprecedented Mo-organic molecular cage built on interesting {MoVI2O5} secondary building blocks and BTC ligands, which has been successfully synthesized and systematically characterized, presents the first example of an isopolyoxomolybdates(vi)-organic molecular cage. An investigation into the related Cs+-exchange experiment was performed in detail.
Topics & Concepts
SBusCageOctahedronCrystallographyChemistryNanotechnologyMaterials scienceOrganic chemistryCrystal structureMetal-organic frameworkCombinatoricsAdsorptionMathematicsPolyoxometalates: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesMetal-Organic Frameworks: Synthesis and Applications