Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion
Thomas Reuter, Ayla Kruse, Roland Schoch, Stefan Lochbrunner, Matthias Bauer, Katja Heinze
Abstract
Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(ii) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(ii) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap.
Topics & Concepts
CarbeneChelationChemistryRing (chemistry)CrystallographyStereochemistryInorganic chemistryCatalysisOrganic chemistryOrganometallic Complex Synthesis and CatalysisN-Heterocyclic Carbenes in Organic and Inorganic ChemistryMagnetism in coordination complexes