Exploring anti-corrosion properties and rheological behaviour of tannic acid and epoxidized soybean oil-based fully bio-based epoxy thermoset resins
Rubén Teijido, Cristina Monteserín, Miren Blanco, José Luis Larrañaga Odriozola, Miren Itxaso Maguregui Olabarria, José Luis Vilas‐Vilela, S. Lanceros‐Méndez, Qi Zhang, Leire Ruiz‐Rubio
Abstract
This research explores the physicochemical attributes of a fully bio-epoxy thermoset aimed at serving as an anti-corrosion coating for safeguarding carbon steel structures in marine environments. Throughout this investigation, various epoxy thermosets formulations, based on epoxidized soybean oil (ESO) and tannic acid (TA), were synthesized by adjusting the initial ratios of epoxide:hydroxyl groups (epoxy:OH). These formulations were subsequently applied onto carbon steel substrates and subjected to thermal curing at moderate temperatures (170 °C) to evaluate their anti-corrosion effectiveness using electrochemical impedance spectroscopy (EIS). The examination of the total impedance values derived from EIS Bode diagrams (>10 6 Ω) revealed a notable anti-corrosion efficacy that endured over several months of immersion in 3.5 wt% NaCl solutions. In addition to electrochemical assessment, a rheological analysis was conducted to determine the optimal curing temperature for each formulation and to track the evolution of their mechanical properties throughout the curing process. Furthermore, the progression of corrosion at the coating-metal interphase was quantified using samples featuring artificially created notches to facilitate rapid water penetration, reaching the protected surface. Moreover, cross-cut and pull-off adhesion tests were conducted on coatings cured with various epoxide:hydroxyl ratios, yielding exceptional results on carbon steel substrates. Overall, a great potential for anti-corrosion protection has been demonstrated on the developed fully bio-based coatings with tuneable mechanical properties, regarding the initial component ratio, to reach the specific requirements for specific applications. • Easy development of bio-based epoxy resin using epoxidized soybean oil and tannic acid, eco-friendly natural substances. • Comprehensive analysis of anti-corrosion properties of bio-based epoxy resins, monitored over several months. • Demonstrates protection equal or superior to petroleum-based counterparts, even in harsh environments. • Insights into coating-steel interaction mechanisms yielding superior adhesion strengths, matching commercial alternatives.