Litcius/Paper detail

A strong fracture-resistant high-entropy alloy with nano-bridged honeycomb microstructure intrinsically toughened by 3D-printing

Punit Kumar, Sheng Huang, David H. Cook, Kai Chen, Upadrasta Ramamurty, Xipeng Tan, Robert O. Ritchie

2024Nature Communications88 citationsDOIOpen Access PDF

Abstract

Abstract Strengthening materials via conventional “top-down” processes generally involves restricting dislocation movement by precipitation or grain refinement, which invariably restricts the movement of dislocations away from, or towards, a crack tip, thereby severely compromising their fracture resistance. In the present study, a high-entropy alloy Al 0.5 CrCoFeNi is produced by the laser powder-bed fusion process, a “bottom-up” additive manufacturing process similar to how nature builds structures, with the microstructure resembling a nano-bridged honeycomb structure consisting of a face-centered cubic ( fcc ) matrix and an interwoven hexagonal net of an ordered body-centered cubic B2 phase. While the B2 phase, combined with high-dislocation density and solid-solution strengthening, provides strength to the material, the nano-bridges of dislocations connecting the fcc cells, i.e ., the channels between the B2 phase on the cell boundaries, provide highways for dislocation movement away from the crack tip. Consequently, the nature-inspired microstructure imparts the material with an excellent combination of strength and toughness.

Topics & Concepts

MicrostructureMaterials scienceAlloyDislocationComposite materialFracture toughnessCubic crystal systemNano-Honeycomb structurePhase (matter)ToughnessGrain boundaryStrengthening mechanisms of materialsCondensed matter physicsOrganic chemistryPhysicsChemistryHigh Entropy Alloys StudiesAdditive Manufacturing Materials and ProcessesHigh-Temperature Coating Behaviors