A new route to porous metal–organic framework crystal–glass composites
Shichun Li, Shuwen Yu, Sean M. Collins, Duncan N. Johnstone, Christopher W. Ashling, Adam F. Sapnik, Philip A. Chater, Dean S. Keeble, Lauren McHugh, Paul A. Midgley, David A. Keen, Thomas D. Bennett
Abstract
A lower temperature route to metal–organic framework crystal–glass composites is presented. Specifically, the annealing pre-formed ZIF-62 glass with a crystalline MOF above<italic>T</italic><sub>g</sub>will enable formation of a greatly expanded range of materials.
Topics & Concepts
Materials scienceMetal-organic frameworkAnnealing (glass)PorosityComposite materialCrystal (programming language)MetalAmorphous metalCrystal structurePorous glassCrystallographyMetallurgyChemistryOrganic chemistryComputer scienceAdsorptionProgramming languageAlloyMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes