Open metal site (OMS)-inspired investigation of adsorption and catalytic functions in a porous metal–organic framework (MOF)
Anand Mohan Yadav, Sarita Kumari, Preety Yadav, Arpan Hazra, Anindita Chakraborty, Prakash Kanoo
Abstract
O vapour, while a gated isotherm was recorded with MeOH. After realizing the favourable interaction of 1' with polar solvent molecules, we have used Mn(II) OMSs in 1' for efficient cyanosilylation reactions of aromatic aldehydes. We have recorded 100% conversion for eight aromatic aldehydes, while several other aldehydes showed appreciable conversion. Notably, the recorded conversions in the case of many substrates are higher than those for many other reported MOF catalysts.
Topics & Concepts
Metal-organic frameworkCatalysisChemistryBenzeneAdsorptionSolventDicarboxylic acidDimethylformamideCarboxylateMoleculeInorganic chemistryMetalPolymer chemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCarbon dioxide utilization in catalysis