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Exploring the Potential Applications of Lanthanide-Based Double Perovskite in Remote Pressure and Temperature Sensing

Xin Liu, Guangming Niu, Xiaowei Wang, Jutao Jiang, Laizhi Sui, Xiangyu Zeng, Yutong Zhang, Li Che, Guorong Wu, Kaijun Yuan, Xueming Yang

2023The Journal of Physical Chemistry Letters21 citationsDOI

Abstract

Remote optical sensing with nondestructive, fast, and accurate detection capabilities is a powerful noncontact method widely used in natural, industrial, and biological fields. In this work, Cs 2 NaErCl 6 double perovskite was synthesized via a hydrothermal method. The pressure-dependent photoluminescence (PL) lifetime of Er 3+ in the range of 0–20 GPa was investigated, demonstrating its potential for pressure monitoring. The high-pressure relative sensitivity ( S R ) is ∼18.45% GPa –1 . Temperature measurements were conducted using the fluorescence intensity ratio (FIR) of the thermal couple energy level (TCEL) and the nonthermal couple energy level (NTCEL) of Er 3+ across a temperature range of 100–660 K, with a maximum S R of 5.36% K –1 . By combining MXene with Cs 2 NaErCl 6 and recording the FIR of Cs 2 NaErCl 6 under 1550 nm excitation, the photothermal conversion temperature of MXene can be accurately determined. These findings highlight the potential of Cs 2 NaErCl 6 for remote pressure and temperature sensing, particularly in the biomedical field.

Topics & Concepts

Materials sciencePhotoluminescenceAtmospheric temperature rangeHydrothermal circulationPhotothermal therapyLuminescencePerovskite (structure)Temperature measurementOptoelectronicsExcitationFluorescenceRange (aeronautics)Work (physics)Atmospheric pressureLanthanideAnalytical Chemistry (journal)OpticsNanotechnologyChemistryPhysicsThermodynamicsComposite materialMeteorologyGeologyCrystallographySeismologyOrganic chemistryQuantum mechanicsIonChromatographyPerovskite Materials and ApplicationsMXene and MAX Phase Materials2D Materials and Applications
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