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Genomic DNA-mediated formation of a porous Cu<sub>2</sub>(OH)PO<sub>4</sub>/Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>·8H<sub>2</sub>O rolling pin shape bifunctional electrocatalyst for water splitting reactions

Harjinder Singh, Imtiaz Ahmed, Rathindranath Biswas, Shouvik Mete, Krishna Kamal Halder, Biplab Banerjee, Krishna Kanta Haldar

2022RSC Advances23 citationsDOIOpen Access PDF

Abstract

O composite was controlled and stabilized by the DNA biomolecules. This porous rolling pin shape composite was explored towards electrocatalytic water oxidation for both OER and HER as a bi-functional catalyst. The as-prepared catalyst exhibited a very high OER and HER activity compared to its various counterparts in the absence of an external binder (such as Nafion). The synergistic effects between Cu and Co metals together with the porous structure of the composite greatly helped in enhancing the catalytic activity. These outcomes undoubtedly demonstrated the beneficial utilization of the genomic DNA-stabilised porous electrocatalyst for OER and HER, which has never been observed.

Topics & Concepts

ChemistryDNACrystallographyBiochemistryElectrocatalysts for Energy ConversionCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions
Genomic DNA-mediated formation of a porous Cu<sub>2</sub>(OH)PO<sub>4</sub>/Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>·8H<sub>2</sub>O rolling pin shape bifunctional electrocatalyst for water splitting reactions | Litcius