Radical boron migration of allylboronic esters
Xiangzhang Tao, Shengyang Ni, Lingyu Kong, Yi Wang, Yi Pan
Abstract
consecutive 1,2-boron migrations and Smiles-type rearrangement to furnish a variety of terminally functionalized alkyl boronates. Several types of migrating variations of heteronuclei radicals and dearomatization processes are also tolerated, allowing for further elaboration of highly functionalized boron-containing frameworks.
Topics & Concepts
BoronRadicalChemistryAllylic rearrangementAlkylCarbon atomCarbon fibersCombinatorial chemistryMedicinal chemistryOrganic chemistryCatalysisMaterials scienceComposite materialComposite numberOrganoboron and organosilicon chemistryRadical Photochemical ReactionsCatalytic C–H Functionalization Methods