Divergent synthesis of carbamates and <i>N</i>-methyl carbamates from dimethyl carbonate and nitroarenes with Mo(CO)<sub>6</sub> as a multiple promoter
Tongshun An, Chenwei Liu, Weiheng Yuan, Xiaowen Qin, Zhiping Yin
Abstract
A switchable base-controlled divergent synthesis of carbamates and N -methyl carbamates from nitroarenes and dialkyl carbonates was realized by using Mo(CO) 6 as a multiple promoter.
Topics & Concepts
Dimethyl carbonateCarbonateChemistryMedicinal chemistryOrganic chemistryCatalysisCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisChemical Synthesis and Reactions