Stereomutation and chiroptical bias in the kinetically controlled supramolecular polymerization of cyano-luminogens
Lucía López‐Gandul, Cristina Naranjo, Cecilia Sánchez, Rafael Rodríguez, Rafael Gómez, Jeanne Crassous, Luis Sánchez
Abstract
The emissive features of supramolecular polymers formed by cyano-luminogens depends on the nature of the central aromatic unit. Intramolecular H-bonded species influence the chiroptical properties and the resulting aggregated species can be kinetically controlled.
Topics & Concepts
Supramolecular chemistryPolymerizationChemistryPhotochemistryPolymer chemistryOrganic chemistryMoleculePolymerSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applicationsLuminescence and Fluorescent Materials