NaCl nanocrystal-encapsulated carbon dots as a solution-based sensor for phosphorescent sensing of trace amounts of water in organic solvents
Manivannan Madhu, Wei‐Lung Tseng
Abstract
ions serve as a nucleation site to trigger NaCl nanocrystal formation. Electron microscopy and spectroscopy techniques demonstrate the embedment of PDDA-CDs into NaCl nanocrystals (PDDA-CDs@NaCl). The PDDA-CDs@NaCl exhibited excitation-independent phosphorescence and excitation-dependent fluorescence in ethanol, methanol, dimethyl sulfoxide, and dimethylformamide. In four different organic solvents, the phosphorescence QYs and lasting times of PDDA-CDs@NaCl range from 23 to 35% and 1.2 to 1.5 s, respectively. Once trace amounts of water are present in an organic solvent, the water-induced dissolution of NaCl nanocrystals switches off the phosphorescence of PDDA-CDs@NaCl. It was found that PDDA-CDs@NaCl was capable of detecting as low as 0.25% v/v water in ethanol and 0.125% v/v water in methanol. The above-discussed results provide fundamental insights regarding the embedment of phosphorescent CDs into a solid matrix as a solution-based sensor.