Highly efficient synergistic CO<sub>2</sub> conversion with epoxide using copper polyhedron-based MOFs with Lewis acid and base sites
Jiaming Gu, Xiaodong Sun, Xinyao Liu, Yuan Yang, Hongyan Shan, Yunling Liu
Abstract
The catalytic performances and effect of LASs and LBSs of four isomorphous Cu-PMOFs in CO<sub>2</sub> cycloaddition reaction were systematically studied. JLU-Liu21 exhibited significant catalytic efficiency, remarkable recyclability and catalytic stability.
Topics & Concepts
CatalysisLewis acids and basesPolyhedronEpoxideCycloadditionCopperChemistryBase (topology)Materials scienceCombinatorial chemistryOrganic chemistryMathematicsGeometryMathematical analysisMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications