Regioselective synthesis of N-containing polycyclic compounds <i>via</i> radical annulation cyclization of 1,7-dienes with aldehydes
Jia-Li Sui, Long‐Jin Zhong, Biquan Xiong, Kewen Tang, Yu Liu
Abstract
]quinolinone derivatives by sequential formation of three new carbon-carbon bonds. Additionally, this radical cascade cyclization can selectively convert aldehydes into aroyl/primary aliphatic acyl radicals and secondary or tertiary alkyl radicals.
Topics & Concepts
AnnulationRegioselectivityChemistryAlkylationAcylationOrganic chemistryRadical cyclizationCascadeCombinatorial chemistryCatalysisChromatographyRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsCatalytic C–H Functionalization Methods