Litcius/Paper detail

Turning Waste into Value: Potassium‐Promoted Red Mud as an Effective Catalyst for the Hydrogenation of CO<sub>2</sub>

Artem Russkikh, Genrikh Shterk, B.H. Alsolami, Bandar A. Fadhel, Adrián Ramírez, Jorge Gascón

2020ChemSusChem41 citationsDOI

Abstract

Abstract Since 1887, red mud has been an unavoidable waste derived from the production of alumina in the Bayer process. Because of its high alkalinity and metal loading, red mud disposal and storage constitute a significant environmental risk. With worldwide storage capacity reaching its limits and no alternatives to the Bayer Process, the development of methods for the valorization of red mud is a must. In this study, red mud is converted into an efficient catalyst for the valorization of CO 2 . By simple potassium promotion, 45 % conversion of CO 2 with a light olefin (C 2 –C 4 ) selectivity of 36 % is achieved at 375 °C, 30 bar, and 9600 mL g −1 h −1 , matching the performance of some of the best catalysts reported to date.

Topics & Concepts

Red mudAlkalinityCatalysisPotassiumPulp and paper industryBayer processChemistryWaste managementEnvironmental scienceOrganic chemistryEngineeringAluminiumPhysical chemistryCatalysts for Methane ReformingBauxite Residue and UtilizationAmmonia Synthesis and Nitrogen Reduction