Tuning electronic structure of MOF-based solid-state electrolytes to activate dormant lithium and facilitate ion transport kinetics towards lithium metal batteries
Qing Liu, Qi An, Kun Zeng, Mou Yang, Haiye Zhu, Xilin Liang, Guiquan Zhao, Mengjiao Sun, Yunchun Zha, Yang Li, Lingyan Duan, Genfu Zhao, Yongjiang Sun, Hong Guo
Abstract
A MOF(Ti-Co) membrane with abundant catalytic sites enhances Li + transport and anion confinement. Spontaneous redox boosts charge-transfer kinetics, improves Li + utilization and suppresses dendrite formation, improving electrochemical performance.
Topics & Concepts
Lithium (medication)KineticsElectrochemistryElectrolyteElectrochemical kineticsRedoxIonIon transporterDendrite (mathematics)Materials scienceCatalysisInorganic chemistryLithium metalFast ion conductorElectrodeChemistryChemical engineeringPhysical chemistryOrganic chemistryEngineeringGeometryMedicineEndocrinologyMathematicsPhysicsQuantum mechanicsAdvancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced battery technologies research